cloud point extraction and spectrophotometric determination of cadmium in some vegetables

نویسندگان

foroozan hasanpour

zahra alimirzaei

masoumeh taei

hamed karimi

r. samimi

چکیده

cloud point extraction and spectrophotometric determination of trace quantities of cadmium in some vegetables have been developed. the research area for vegetables analysis was near to the zarin shahr where the soil received heavy metals from the esfahan steel company. cloud point extraction used dithizone as complexing agent and non ionic surfactant triton-x114 as micellar phase. several important variables affecting the separation and determination process were optimized. under optimized conditions calibration graph was linear in the range of 1.0-180 ng ml-1 with detection limit of 0.2 ng ml-1. preconcentration of 10 ml of samples gave an enhancement factor of 50. the proposed method was applied for determination of cd(ii) in vegetable samples with satisfactory results.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Selective Cloud Point Extraction for the Spectrophotometric Determination of Cetylpyridinium Chloride in Pharmaceutical Formulations

In this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (CPC) in pharmaceutical products using cloud point extraction (CPE) technique. The method is based on cloud point extraction of the CPC in alkali conditions using of nonionic surfactant Triton X-114. Under selected conditions, the calibration ...

متن کامل

Selective Cloud Point Extraction for the Spectrophotometric Determination of Cetylpyridinium Chloride in Pharmaceutical Formulations

In this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (CPC) in pharmaceutical products using cloud point extraction (CPE) technique. The method is based on cloud point extraction of the CPC in alkali conditions using of nonionic surfactant Triton X-114. Under selected conditions, the calibration ...

متن کامل

Determination of lead and cadmium in water samples by cloud point extraction prior to flame atomic absorption spectrometry determination

Pb and Cd in water samples were determined by cloud point extraction (CPE) with sodiumdiethyldithiocarbamate (DDTC) as the chelating agent and octylphenoxypolyethanl (Triton X-114) asthe surfactant prior to flame atomic absorption spectrometry (FAAS) determination. The main factorsof affecting the extraction and detection processes were optimized. The preconcentration of 10 mL ofstandard soluti...

متن کامل

selective cloud point extraction for the spectrophotometric determination of cetylpyridinium chloride in pharmaceutical formulations

in this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (cpc) in pharmaceutical products using cloud point extraction (cpe) technique. the method is based on cloud point extraction of the cpc in alkali conditions using of nonionic surfactant triton x-114. under selected conditions, the calibration ...

متن کامل

Spectrophotometric determination of uranium in water samples after cloud point extraction using nonionic surfactant Triton X-114

A cloud point extraction process using the nonionic surfactant Triton X-114 to extracturanium from aqueous solutions was investigated. The method is based on the complexationreaction of uranium with Arsenazo III and micelle-mediated extraction of the complex. Theoptimal extraction and reaction conditions (e.g., pH, reagent concentration, effect of time) werestudied, and the analytical character...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
iranian journal of analytical chemistry

ناشر: payame noor university, iran

ISSN 2383-2207

دوره 1

شماره 1 2013

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023